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Item type:Publication, A Review on the Development of Biopolymer Nanocomposite-Based Triboelectric Nanogenerators (Bio-TENGs)(American Chemical Society, 2023-07-25)Triboelectric nanogenerators (TENGs) are electronic devices capable of harvesting low-frequency mechanical motions to produce electrical energy through the triboelectrification effect. A great number of electronic devices, such as wearable devices, implantable medical devices, and monitoring sensors, among others, use conventional power sources such as batteries and capacitors. They are usually toxic, nondegradable, and hard to recycle, representing human and environmental hazards. In addition, conventional batteries and capacitors are usually rigid, heavy, and not suitable for the fabrication of portable and flexible devices. TENGs appear as a promising option to be used in the development of light, portable, and self-powered electronic devices. TENGs were first developed using synthetic polymers such as polytetrafluoroethylene (PTFE), fluorinated ethylene propylene (FEP), polydimethylsiloxane (PDMS), and polyimide (Kapton) for the fabrication of the active surfaces that store charge. Bio-TENGs have been fabricated using biopolymers such as cellulose, silk, and chitosan. These Bio-TENGs take advantage of the inherent biodegradability and biocompatibility of biopolymers. In order to improve the capability of biopolymer-based surfaces to store electrostatic charge, several treatments are reported, including the incorporation of nanoparticles and surface treatments. These biopolymer-based active surfaces with improved properties allow Bio-TENGs to achieve output performances similar to those reported for synthetic TENGs. Bio-TENGs have been used in a wide range of applications, such as human monitoring systems, tissue engineering, electronic devices, and industrial-level flooring, among others. This review is focused on the development of Bio-TENGs. The different types of biopolymers used for the fabrication of active surfaces are described and classified as protein-based, polysaccharide-based, and synthetic-based biopolymers. The different strategies used for improving the triboelectric properties of biopolymer-based surfaces are presented, along with the resulting output performance of Bio-TENGs. The reported applications for these Bio-TENGs are also discussed. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Recent Progress in Polysaccharide-Based Materials for Energy Applications: A Review(American Chemical Society, 2025-03-05)In recent years, polysaccharides have emerged as a promising alternative for the development of environmentally friendly materials. Polysaccharide-based materials have been mainly studied for applications in the food, packaging, and biomedical industries. However, many investigations report processing routes and treatments that enable the modification of the inherent properties of polysaccharides, making them useful as materials for energy applications. The control of the ionic and electronic conductivities of polysaccharide-based materials allows for the development of solid electrolytes and electrodes. The incorporation of conductive and semiconductive phases can modify the permittivities of polysaccharides, increasing their capacity for charge storage, making them useful as active surfaces of energy harvesting devices such as triboelectric nanogenerators. Polysaccharides are inexpensive and abundant and could be considered as a suitable option for the development and improvement of energy devices. This review provides an overview of the main research work related to the use of both common commercially available polysaccharides and local native polysaccharides, including starch, chitosan, carrageenan, ulvan, agar, and bacterial cellulose. Solid and gel electrolytes derived from polysaccharides show a wide range of ionic conductivities from 0.0173 × 10-3 to 80.9 × 10-3 S cm-1. Electrodes made from polysaccharides show good specific capacitances ranging from 8 to 753 F g-1 and current densities from 0.05 to 5 A g-1. Active surfaces based on polysaccharides show promising results with power densities ranging from 0.15 to 16 100 mW m-2. These investigations suggest that in the future polysaccharides could become suitable materials to replace some synthetic polymers used in the fabrication of energy storage devices, including batteries, supercapacitors, and energy harvesting devices.3
