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Item type:Publication, Influence of the source of starch and plasticizers on the environmental burden of starch-Brazil nut fiber biocomposite production: A life cycle assessment approach(Elsevier, 2020-12-30)Amidst the global plastic pollution crisis, bio-based polymers have been proposed as a potential substitute to tackle this issue. Owed to their biodegradability, biopolymers are generally regarded as eco-friendly during the post-consumer (disposal) stage. However, the environmental burden of the many production processes biopolymers and their components undergo better reflect the sustainable nature of these materials. Previous studies evaluating the Life Cycle Assessment (LCA) of starch-based composites have focused on commercially available starches, although other non-conventional starches can also be used to produce biopolymers. To address this knowledge gap, in the present study we evaluated the LCA of starch-Brazil nut fiber biocomposites prepared with starch from three different sources, Andean potato, corn, and sweet potato, and applying two different plasticizers, glycerol and sorbitol. Results indicated that the starch-based biocomposites were less impacting than conventional PLA-Brazil nut fiber and PP-glass fiber composites. The type of starch and plasticizer significantly influenced the environmental load of the production of the composites. The main drivers of these differences were the multiple agricultural practices, such as irrigation and fertilization, and the crop efficiency for starch extraction. Sorbitol was found to be many times more impacting than glycerol in most categories, which is due to the complex processing of sorbitol and high content in biocomposites with similar mechanical properties than glycerol. Additionally, Brazil nut fibers are presented as an eco-friendly and low-burden natural filler due to their easy processing and agricultural waste origin. The limitations, applications, and significance of the results were discussed. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, NMR and GPC Analysis of Alkyd Resins: Influence of Synthesis Method, Vegetable Oil and Polyol Content(MDPI, 2023-05-01)Alkyd resins are oil-based polymers that have been widely used for generations in the surface coating industry and beyond. Characterization of these resins is of high importance to understand the influence of its components on its behavior, compatibility with other resins, and final quality to ensure high durability. Here, NMR spectroscopy and GPC were used for characterizing differences in the chemical structure, molecular distribution, and dispersity between oil-based and fatty acid-based alkyd polymers made from sacha inchi and linseed oils. Sancha inchi (Plukentia volubilis L.) is a fruit-bearing plant native to South America and the Caribbean, and has a rich unsaturated fatty acid content. The effect of vegetable oil and polyol selection on the synthesis of alkyd resins for coating applications was analyzed. The influence of two different synthesis methods, monoglyceride and fatty acid processes, was also compared. Important structural differences were observed using NMR: one-dimensional spectra revealed the degree of unsaturated fatty acid chains along the polyester backbone, whereas, 2D NMR experiments facilitated chemical shift assignments of all signals. GPC analysis suggested that alkyd resins with homogeneous and high molecular weights can be obtained with the fatty acid process, and that resins containing pentaerythritol may have uniform chain lengths. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Coupled thermal and dielectric signatures of glycerol-induced structural organization in ulvan-based films(RELX Group (Netherlands), 2026-01-01)1