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Item type:Publication, Photo-induced electron transfer dynamics and its mid-IR modulation of an ethyne bridged donor-acceptor complex(Royal Society of Chemistry, 2025-10-02)Electron transfer (ET) rate in donor–bridge–acceptor (DBA) complexes is modulated by the alkyne bridge vibrational excitation. Torsion angle ( θ ) offers selectivity in accessing locally-excited, acceptor-centered (S 2 ) state of the DBA complex.1