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Item type:Publication, Bacterial-Polymer-Based Electrolytes: Recent Progress and Applications(American Chemical Society, 2020-12-28)Bacteria can naturally synthesize a wide range of biopolymers that have appealing material properties for numerous applications. In the past decade, the development of green electronics based on bacterial polymers has gained major attention. Polymer electrolytes are key components in electrochemical devices owing to their mechanical properties, thermal stability, and ionic conductivity. The present review focuses on the recent progress of bacterial-polymer-based electrolytes and their applications in electrochemical energy conversion and storage. First, we described the ion transfer mechanism of polymer electrolytes and the multiple approaches for improving ionic conductivity and mechanical properties. Then, we summarized the composition, performance, and approaches applied for the development of multiple bacterial polymer electrolytes, namely, polysaccharides, polyanhydrides, and polyesters. Lastly, the practical applications of bacterial-polymer-based electrolytes in electrochemical energy storage and conversion, namely, fuel cells, batteries, supercapacitors, and other electrochemicals, are reviewed. Bacterial polymer electrolytes are presented as a fruitful, eco-friendly, and high-performance alternative for traditional solid polymer electrolytes. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Environmental pollution with antifouling paint particles: distribution, ecotoxicology, and sustainable alternatives(Elsevier, 2021-08-01)Antifouling paint particles (APPs) are a type of paint particle loaded with toxic biocidal compounds. The present review focused on the current knowledge in respect of the abundance, distribution, and ecotoxicological effects of APPs in the marine environment. Also, the recent advances in nontoxic biobased antifouling paints were discussed as potential alternatives to contemporary marine coatings. The presence of APPs is mainly associated with boat maintenance in boatyards and port areas. Conventional microplastic assessments showed a significant contribution of paint particles to the morphological composition. Moreover, recent ecotoxicological studies demonstrated that environmental concentrations of APPs induce mortality (LC50) in sediment dwellers and macroinvertebrates. Novel biocides from natural sources and biopolymer binders in the formulation of antifouling paints are proposed as potential alternatives to conventional antifouling paints. The toxicity of most natural biocides is negligible to nontargeted species, while biopolymers are expected to prevent the formation of APPs.