3. Producción
Browse
6 results
Search Results
- Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effect of polyalcohols on the anticorrosive behaviour of alkyd coatings prepared with drying oils(Elsevier, 2020-08-01)Alkyd paints contain resins derived from vegetable oils. Alkyd resins have regained their importance since they are mostly composed of bio-based constituents recovered from biofuels production and agro-industrial waste. The anticorrosive performance of medium alkyd paints modified with Sacha inchi and linseed oils, and different ratios of glycerol and pentaerythritol, were compared by accelerated corrosion tests (Salt Fog and Sulphur Dioxide tests). This study focuses on comparing the effect of polyalcohol and oil type on physicochemical properties of resin solutions and cured films, and consequently, on the anticorrosive behaviour of paints prepared with the resins under study. Results showed that the mixture of pentaerythritol and Sacha inchi oil improves alkyd resin properties and enhance the anticorrosive performance of alkyd paints in accelerated weathering tests. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Low viscosity alkyd resins based on trimethylolpropane and Peruvian oil(Springer Science and Business Media B.V., 2021-06-01)The high-unsaturated fatty acid content of Sacha inchi oil (SIO), a perennial plant originally from Peru, has turned it into a potential raw material for the production of alkyd resins. In this study, different proportions of multifunctional polyols were used to prepare air-drying resins. Physicochemical characteristics (acid value, viscosity, colour, density, drying time, and hardness) of alkyds were evaluated. Moreover, FT-IR, TG–DTA, 1H-NMR and 13C-NMR characterization techniques were used. SIO-based alkyd resins prepared with trimethylolpropane exhibited low viscosities, suitable for preparing more manageable high solids protective coatings. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Microwave-assisted synthesis of alkyd resins using response surface methodology(Elsevier BV, 2022-11-28)Long alkyd resins for artistic applications were prepared by microwave synthesis of high-unsaturated vegetable oils. In this work, response surface method using split-plot optimal design was applied to optimize alkyd resin's acid value. Oil vegetable source (Sacha inchi and Linseed oil), temperature (200–240 °C), reaction time (4–12 min), and benzoic acid were evaluated as independent variables. Long alkyds resins with lower acid value considered optimal were characterized by FTIR and 1H-RMN techniques. Physicochemical properties, like color, viscosity, and drying time were assessed as well. Synthesis of alkyd resins from sacha inchi oil required less time and energy in comparison with linseed oil ones. Alkyd resins prepared with Sacha inchi oil for 210 °C and 12 min using 11.67 kJ/g at esterification stage provided a lower acid value (14 mgKOH/g), viscosity (W-X bubble Gardner), and Gardner scale color (11) in comparison with linseed oil. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, NMR and GPC Analysis of Alkyd Resins: Influence of Synthesis Method, Vegetable Oil and Polyol Content(MDPI, 2023-05-01)Alkyd resins are oil-based polymers that have been widely used for generations in the surface coating industry and beyond. Characterization of these resins is of high importance to understand the influence of its components on its behavior, compatibility with other resins, and final quality to ensure high durability. Here, NMR spectroscopy and GPC were used for characterizing differences in the chemical structure, molecular distribution, and dispersity between oil-based and fatty acid-based alkyd polymers made from sacha inchi and linseed oils. Sancha inchi (Plukentia volubilis L.) is a fruit-bearing plant native to South America and the Caribbean, and has a rich unsaturated fatty acid content. The effect of vegetable oil and polyol selection on the synthesis of alkyd resins for coating applications was analyzed. The influence of two different synthesis methods, monoglyceride and fatty acid processes, was also compared. Important structural differences were observed using NMR: one-dimensional spectra revealed the degree of unsaturated fatty acid chains along the polyester backbone, whereas, 2D NMR experiments facilitated chemical shift assignments of all signals. GPC analysis suggested that alkyd resins with homogeneous and high molecular weights can be obtained with the fatty acid process, and that resins containing pentaerythritol may have uniform chain lengths. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Alkyds with Artistic Applications Based on Drying Oils, Multifunctional Polyalcohols and Different Polybasic Acids(John Wiley and Sons Inc, 2023-04-20)Today's requirements in the art field have challenged researchers to create artistic paintings with attractive appearance and long-term color stability. Alkyd-based art mediums have become an important group in the art field, because of their similar characteristics to traditional oils and exceptional drying properties. In this work, high solid alkyd-based art mediums have been synthesized by the monoglyceride and acidolysis processes. Multifunctional polyols and high unsaturated fatty acid sources were compared and used for alkyd synthesis. The use of a non-traditional oil of Peruvian origin is proposed. Resins have been characterized according to their physicochemical (acid number, viscosity, color and density) and drying properties. Drying tendencies were verified with the use of quartz crystal microbalance. Also, the behavior of the art mediums mixed with commercial oil paintings and a dry pigment, have also been evaluated. Results indicate that resins containing the polyol with the highest functionality are more viscous and have fewer tendencies to yellowing, while non-traditional Peruvian oil is the best option for creating light-colored art mediums. Alkyd mediums prepared by the monoglyceride method gave to oil paintings better characteristics and drying behavior on canvas. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Microwave-assisted modification of a solid epoxy resin with a Peruvian oil(Elsevier BV, 2025-09-01)A solid epoxy resin was modified with drying vegetable oils via microwave heating to produce one-component epoxy ester resins. These hybrid bio-based resins have an epoxy network that cures at room temperature due to the auto-oxidative capacity of unsaturated fatty acid chains. The influence of the fatty acid source, temperature, and reaction time on viscosity was evaluated using a response surface design. Structure (Fourier transform infrared (FTIR) spectroscopy and proton nuclear magnetic resonance ( 1 H NMR)), drying behavior, thermal stability (thermogravimetry/ differential thermal analysis (TG/DTG)), and molecular weight distribution (gel permeation chromatography (GPC)) of selected resins were also studied. Paints prepared with representative epoxy ester resins were analyzed to compare the effect of the fatty acid source on anticorrosive properties by electrochemical impedance and salt spray tests. The design of experiments simplified the selection of synthesis conditions to obtain optimal resin film properties. Microwaved-synthesized epoxy ester resins prepared with Peruvian oil are potential raw materials for developing functional anticorrosive paints, as they provide the best corrosion resistance . Its high unsaturation content gives sacha inchi oil the curing properties needed to replace linseed oil in the coatings industry .1