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    Dissolution kinetics and solubilities of copper sulfides in cyanide and hydrogen peroxide leaching: applications to increase selective extractions
    (Elsevier, 2021-11-01)
    Accurate quantification of secondary and primary sulfide minerals is fundamental for resource evaluation, ore processing, and long-term sustainability of mining operations. In addition to visual mapping and automated mineral quantification, chemical analysis can also be harnessed to characterize the mineralogy of ore deposits. By evaluating the conditions in which certain minerals can be selectively dissolved from others, a chemical evaluation could provide geochemical speciation data of low-abundance minerals, such as copper/iron sulfides present in low-grade copper ores. The selective dissolution of copper sulfide minerals is, however, understudied. Here, we evaluate the use of potential selective dissolution conditions to differentiate supergene copper sulfides from hypogene copper sulfides. By characterizing the dissolution kinetics of chalcocite, covellite, bornite, enargite, chalcopyrite, and pyrite concentrates, we found that alkaline cyanidation (and not hydrogen peroxide or acid leaching in the presence of oxidizing agents) selectively dissolves supergene copper sulfides, which can be applied in a sequential extraction scheme to estimate the sulfide mineralogy of tailings samples. Cyanide completely dissolved chalcocite and covellite within 5–15 min, whereas dissolution in acid oxidative media only partially dissolved copper sulfides. Pyrite, chalcopyrite, enargite, and bornite under 0.5% KCN leaching (1 mg/mL) for 10 min showed approximately 1, 10, 30, and 40% of copper recovery, respectively. Cyanide leaching applied in sequential extractions of porphyry copper tailings samples from the Piuquenes impoundment, La Andina, Chile, improved the selective dissolution of secondary sulfides compared to a previously proposed hydrogen peroxide dissolution method, thus allowing their differentiation from primary sulfide minerals. The selective leaching of supergene sulfides by cyanidation provides a cheap and efficient method to estimate the copper sulfide mineralogy in copper ores, facilitating the sustainability and resource evaluation of mining operations.
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    SoTL in Latin America: Bridging Cultures, Transforming Teaching and Learning
    (University of Calgary, 2025-05-01)
    The Scholarship of Teaching and Learning (SoTL) is rapidly emerging as a transformative force in Latin American higher education, bridging diverse cultures and reshaping pedagogical practices to meet the region's unique challenges. Inspired by Paulo Freire's critical pedagogy—which emphasizes education as a means of social transformation and empowerment—this article examines how SoTL integrates interculturality, identity, and equity into university education across Latin America. By aligning teaching and learning with the rich sociocultural realities of the region, SoTL effectively addresses educational inequalities and promotes inclusive access to learning opportunities. Institutions have embraced innovative practices such as faculty development programs, the integration of SoTL methodologies across various disciplines, and active student participation in pedagogical innovation. National policies and regional collaborations, notably the formation of LatinSoTL, have further propelled this movement, fostering a culture of reflective practice and continuous improvement. Despite significant advancements, challenges remain. These include the cultural integration of SoTL concepts, heavy faculty workloads, limited interdisciplinary programs, technological disparities, and the imperative to align educational practices with the Sustainable Development Goals (SDGs). Overcoming these obstacles requires sustained efforts in faculty development, investment in technological infrastructure, and supportive policies that recognize and reward teaching excellence. The impact of SoTL is evident in the growing valuation of teaching, increased student engagement, and policy shifts that prioritize teaching in academic evaluations. By embracing SoTL and the principles of Freire's critical pedagogy, Latin American institutions not only improve educational outcomes, but also contribute valuable insights to the global discourse on higher education. This article highlights the critical role of culturally responsive education in transforming teaching and learning, ultimately bridging cultures and fostering social change throughout the region. RESUMEN La investigación académica sobre la docencia y el aprendizaje (scholarship of teaching and learning, SoTL) está emergiendo rápidamente como una fuerza transformadora en la educación superior latinoamericana, estableciendo puentes entre diversas culturas y reformulando las prácticas pedagógicas para enfrentar los desafíos particulares de la región. Inspirado en la pedagogía crítica de Paulo Freire—la cual enfatiza la educación como una vía hacia la transformación social y el empoderamiento—este artículo analiza cómo SoTL integra la interculturalidad, la identidad y la equidad en la educación universitaria a lo largo de América Latina. Al alinear la enseñanza y el aprendizaje con las complejas realidades socioculturales regionales, SoTL aborda eficazmente las desigualdades educativas y promueve un acceso inclusivo a las oportunidades de aprendizaje. Diversas instituciones han adoptado prácticas innovadoras, tales como programas de desarrollo académico para docentes, la integración de metodologías SoTL en múltiples disciplinas y la participación activa de estudiantes en innovaciones pedagógicas. Las políticas nacionales y colaboraciones regionales, particularmente mediante la conformación de redes como LatinSoTL, han impulsado aún más este movimiento, fomentando una cultura de práctica reflexiva y mejora continua. Pese a estos importantes avances, subsisten diversos desafíos. Entre ellos destacan la integración cultural de los conceptos de SoTL, la sobrecarga laboral docente, la limitada disponibilidad de programas interdisciplinarios, las brechas tecnológicas y la necesidad de alinear las prácticas educativas con los Objetivos de Desarrollo Sostenible (ODS). Superar estos obstáculos requiere esfuerzos sostenidos en la formación docente, inversión en infraestructura tecnológica y políticas institucionales que reconozcan y recompensen la excelencia en la enseñanza. El impacto del SoTL se evidencia en la creciente valoración de la docencia, un mayor compromiso estudiantil y cambios en políticas institucionales que priorizan la docencia en las evaluaciones académicas. Al adoptar el enfoque del SoTL y los principios de la pedagogía crítica freireana, las instituciones latinoamericanas no solo mejoran los resultados educativos, sino que además aportan valiosas perspectivas al discurso global sobre la educación superior. Este artículo enfatiza el rol esencial de la educación culturalmente sensible para transformar los procesos de enseñanza y aprendizaje, promoviendo el diálogo intercultural y favoreciendo el cambio social en toda la region.
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